I tried it with Constraint Proportions on before. I went back to the image file again and apply the cropping, restraining the size to 94px x 99px in CS6 and saved the file without the image resampling.
I just notice when I apply the cropping again in CS5, it cropped the picture slightly differently and got the results I wanted after resampling.
So if I restrained the dimensions when I cropped the image in both C5 and CS6, why is CS6 cropping it differently? I notice there are some extra options in C6 tool bar where you define the cropping measurements, (I'm not in front of the computer right now so this may not be accurate), I think there is an option to crop off white edges or something. Maybe there's a feature that is new I'm overlooking?